Size-Dependent Passivation Shell and Magnetic Properties in Antiferromagnetic/Ferrimagnetic Core/Shell MnO Nanoparticles

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Size-dependent passivation shell and magnetic properties in antiferromagnetic/ferrimagnetic core/shell MnO nanoparticles.

The magnetic properties of bimagnetic core/shell nanoparticles consisting of an antiferromagnetic MnO core and a ferrimagnetic passivation shell have been investigated. It is found that the phase of the passivation shell (gamma-Mn(2)O(3) or Mn(3)O(4)) depends on the size of the nanoparticles. Structural and magnetic characterizations concur that while the smallest nanoparticles have a predomina...

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ژورنال

عنوان ژورنال: Journal of the American Chemical Society

سال: 2010

ISSN: 0002-7863,1520-5126

DOI: 10.1021/ja1021798